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Watch full episodes of Chuck on TheWB.com. Chuck stars Zachary Levi, Yvone Strahovski, Joshua Gomez, Adam Baldwin and Sarah Lancaster about Chuck Bartowski when he opens an e-mail subliminally encoded with government secrets and unwittingly downloads an entire server of sensitive data into his brain. Now, the fate of the world lies in the unlikely hands of a guy who works at a Buy More Electronics store.